Research and Development

@article{Guidote2001b,

title = {Syntheses and characterization of homodinuclear manganese and cobalt complexes bridged by a hemiacetal or by an acetato group in a μ-(η2:η1) bridging mode},

author = {Armando M. Guidote Jr. and Ken-ichi Ando and Yasuhiko Kurusu and Hirotaka Nagao and Yoshiro Masuyama},

url = {https://www.sciencedirect.com/science/article/abs/pii/S0020169301002948},

doi = {10.1016/S0020-1693(01)00294-8},

year  = {2001},

date = {2001-03-07},

journal = {Inorganica Chimica Acta},

volume = {314},

pages = {27-36},

abstract = {The complex [Mn2(BPMAPS)(μ-OAc)2(hemi)]PF6 (1), where hemi is the hemiacetal group, methoxy(2-pyridyl)methoxo, was prepared from bis[3-(2-pyridylmethyleneamino)phenyl] sulfone (BPMAPS), 2-pyridinecarbaldehyde, and manganese(II) acetate in methanol. The complexes Mn2(BPMAPS)(μ-OAc)2(μ-1,1-OAc)(η1-OAc) (2) and Co2(BPMAPS)(μ-OAc)2-[μ-(η2:η1)OAc](η1-OAc) (3) were prepared from manganese(II) acetate and cobalt(II) acetate, respectively, with BPMAPS in methanol. All three complexes were characterized by elemental analysis, FT-IR, MS, UV–Vis spectroscopy, and X-ray crystallography. The manganese ions of complex 1 are bridged by a hemiacetal through the oxygen atom of the alkoxo with the nitrogen atom of the pyridine group coordinating to one of the manganese atoms. The metal ions of complexes 2 and 3 are bridged by acetato groups in μ-1,1 or μ-η2:η1 modes, respectively.},

keywords = {cobalt complex, dinuclear, manganese complex, schiff base type ligand},

pubstate = {published},

tppubtype = {article}

}